Фрази ризику (скорочення R-фрази) визначені у Додатку III європейської Директиви 67/548/EEC: «Характер особливих ризиків притаманних небезпечним речовинам і препаратам. Список був допрацьований і перевиданий тут , де можна переклади іншими мовами ЄС знайти.
Ці фрази ризику застосовуються міжнародно, а не лише в Європі — застосовуються постійні зусилля до повної міжнародної гармонізації.
Фрази ризику Note: Missing R-numbers indicate phrases that have been deleted or replaced by other phrases. Код ФразаR1 Explosive when dryR2 Risk of explosion by shock, friction, fire or other sources of ignitionR3 Extreme risk of explosion by shock, friction, fire or other sources of ignitionR4 Forms very sensitive explosive metallic compoundsR5 Heating may cause an explosionR6 Explosive with or without contact with airR7 May cause fireR8 Contact with combustible material may cause fireR9 Explosive when mixed with combustible materialR10 FlammableR11 Highly flammableR12 Extremely flammableR14 Reacts violently with waterR15 Contact with water liberates extremely flammable gasesR16 Explosive when mixed with oxidising substancesR17 Spontaneously flammable in airR18 In use, may form flammable/explosive vapour-air mixtureR19 May form explosive peroxidesR20 Harmful by inhalationR21 Harmful in contact with skinR22 Harmful if swallowedR23 Toxic by inhalationR24 Toxic in contact with skinR25 Toxic if swallowedR26 Very toxic by inhalationR27 Very toxic in contact with skinR28 Very toxic if swallowedR29 Contact with water liberates toxic gas.R30 Can become highly flammable in useR31 Contact with acids liberates toxic gasR32 Contact with acids liberates very toxic gasR33 Danger of cumulative effectsR34 Causes burnsR35 Causes severe burnsR36 Irritating to eyesR37 Irritating to respiratory systemR38 Irritating to skinR39 Danger of very serious irreversible effectsR40 Limited evidence of a carcinogenic effectR41 Risk of serious damage to eyesR42 May cause sensitisation by inhalationR43 May cause sensitisation by skin contactR44 Risk of explosion if heated under confinementR45 May cause cancerR46 May cause inheritable genetic damageR48 Danger of serious damage to health by prolonged exposureR49 May cause cancer by inhalationR50 Very toxic to aquatic organismsR51 Toxic to aquatic organismsR52 Harmful to aquatic organismsR53 May cause long-term adverse effects in the aquatic environmentR54 Toxic to floraR55 Toxic to faunaR56 Toxic to soil organismsR57 Toxic to beesR58 May cause long-term adverse effects in the environmentR59 Dangerous for the ozone layerR60 May impair fertilityR61 May cause harm to the unborn childR62 Possible risk of impaired fertilityR63 Possible risk of harm to the unborn childR64 May cause harm to breast-fed babiesR65 Harmful: may cause lung damage if swallowedR66 Repeated exposure may cause skin dryness or crackingR67 Vapours may cause drowsiness and dizzinessR68 Possible risk of irreversible effects
Комбінації
Code Combination StatementR14/15 Reacts violently with water, liberating extremely flammable gasesR15/29 Contact with water liberates toxic, extremely flammable gasesR14/15/29 Reacts violently with water, liberating toxic, extremely flammable gasesR20/21 Harmful by inhalation and in contact with skinR20/22 Harmful by inhalation and if swallowedR20/21/22 Harmful by inhalation, in contact with skin and if swallowedR21/22 Harmful in contact with skin and if swallowedR23/24 Toxic by inhalation and in contact with skinR23/25 Toxic by inhalation and if swallowedR23/24/25 Toxic by inhalation, in contact with skin and if swallowedR24/25 Toxic in contact with skin and if swallowedR26/27 Very toxic by inhalation and in contact with skinR26/28 Very toxic by inhalation and if swallowedR26/27/28 Very toxic by inhalation, in contact with skin and if swallowedR27/28 Very toxic in contact with skin and if swallowedR36/37 Irritating to eyes and respiratory systemR36/38 Irritating to eyes and skinR36/37/38 Irritating to eyes, respiratory system and skinR37/38 Irritating to respiratory system and skinR39/23 Toxic: danger of very serious irreversible effects through inhalationR39/24 Toxic: danger of very serious irreversible effects in contact with skinR39/25 Toxic: danger of very serious irreversible effects if swallowedR39/23/24 Toxic: danger of very serious irreversible effects through inhalation and in contact with skinR39/23/25 Toxic: danger of very serious irreversible effects through inhalation and if swallowedR39/24/25 Toxic: danger of very serious irreversible effects in contact with skin and if swallowedR39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowedR39/26 Very Toxic: danger of very serious irreversible effects through inhalationR39/27 Very Toxic: danger of very serious irreversible effects in contact with skinR39/28 Very Toxic: danger of very serious irreversible effects if swallowedR39/26/27 Very Toxic: danger of very serious irreversible effects through inhalation and in contact with skinR39/26/28 Very Toxic: danger of very serious irreversible effects through inhalation and if swallowedR39/27/28 Very Toxic: danger of very serious irreversible effects in contact with skin and if swallowedR39/26/27/28 Very Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowedR42/43 May cause sensitization by inhalation and skin contactR45/46 May cause cancer and heritable genetic damageR48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalationR48/21 Harmful: danger of serious damage to health by prolonged exposure in contact with skinR48/22 Harmful: danger of serious damage to health by prolonged exposure if swallowedR48/20/21 Harmful: danger of serious damage to health by prolonged exposure through inhalation and in contact with skinR48/20/22 Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowedR48/21/22 Harmful: danger of serious damage to health by prolonged exposure in contact with skin and if swallowedR48/20/21/22 Harmful: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowedR48/23 Toxic: danger of serious damage to health by prolonged exposure through inhalationR48/24 Toxic: danger of serious damage to health by prolonged exposure in contact with skinR48/25 Toxic: danger of serious damage to health by prolonged exposure if swallowedR48/23/24 Toxic: danger of serious damage to health by prolonged exposure through inhalation and in contact with skinR48/23/25 Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowedR48/24/25 Toxic: danger of serious damage to health by prolonged exposure in contact with skin and if swallowedR48/23/24/25 Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowedR50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environmentR51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environmentR52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environmentR68/20 Harmful: possible risk of irreversible effects through inhalationR68/21 Harmful: possible risk of irreversible effects in contact with skinR68/22 Harmful: possible risk of irreversible effects if swallowedR68/20/21 Harmful: possible risk of irreversible effects through inhalation and in contact with skinR68/20/22 Harmful: possible risk of irreversible effects through inhalation and if swallowedR68/21/22 Harmful: possible risk of irreversible effects in contact with skin and if swallowedR68/20/21/22 Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowed
R-phrases no longer in use R13: Extremely flammable liquefied gas. R47: May cause birth defects.
Див. також List of S-phrases Material safety data sheet Risk and Safety Statements :Template:R-phrase :Category:R-phrase templates
Посилання Chemical Risk & Safety Phrases in 23 European Languages